WebThis is still the only example in which sequential thiol-ene / thiol-ene reactions operating via inherently different mechanisms have been employed in polymer /materials … This review highlights examples of recent applications of both the radical-mediated … WebFeb 22, 2010 · Further, the thiol-ene reaction is most frequently photoinitiated, particularly for photopolymerizations resulting in highly uniform polymer networks, promoting unique capabilities related to spatial and temporal control of the click reaction. The reaction mechanism and its implementation in various synthetic methodologies, …
Thiol–ene “click” reactions and recent applications in polymer and ...
WebThiol-ene hydrogels have emerged as an attractive class of hydrogels for studying 3D cell biology ... Consequently, cells encapsulated at higher packing density were surrounded by a slightly denser polymer network. While the thiol-ene crosslinking processes did not cause significant cellular damage, the denser local hydrogel mesh inhibited ... WebThis contribution serves as an update to a previous review (Polym.Chem. 2010, 1, 17–36) and highlights recent applications of thiol–ene ‘click’ chemistry as an efficient tool for both polymer/materials synthesis as well as modification.This current contribution covers examples from the literature published up to ca. mid 2013. It is not intended to be … kenway southend
Synthesis of sequence-controlled polymers via sequential ... - Nature
WebSep 22, 2004 · Department of Polymer Science, University of Southern Mississippi, Hattiesburg, Mississippi, 39406Search for more papers by this author. ... One of the major obstacles in traditional free-radical photopolymerization is essentially eliminated in thiol–ene polymerizations because the polymerization occurs in air almost as rapidly as … WebApr 1, 2024 · Triallylated l-glutamic acid and l-tyrosine (A3E amd A3Y) and their tetraallyl derivatives (A4E and A4Y) were synthesized by reactions of l-glutamic acid and l-tyrosine with allyl bromide in the presence of potassium carbonate, respectively.Thiol-ene photopolymerizations of the allylated amino acids and a pentaerythritol-based tetrathiol … WebFeb 11, 2015 · Air-stable primary phosphines were photopolymerized using phosphane–ene chemistry, the phosphorus analogue of the thiol–ene reaction, to fabricate a completely new class of polymer networks. It was demonstrated that the tunable thermal and physical properties accessible using thiol–ene chemistry could also be achieved using an … kenway products